Use as predicative adjective or adverb

When using the superlative as predicative adjective (meaning: put behind the noun it describes) or as adverb the preposition am is to be used.

Some examples  
Er isst am schnellsten von allen. (adverb)
= He eats fastest of them all.
Was mich am meisten störte, war, dass er nie etwas sagte. (adverb)
= What bothers me most is, that he never said anything.
Sein Auto ist am schnellsten. (predicative adjective)
= His car is the fastest.  

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